How to choose the righ laser marking plastic, 355nm laser,532 laser or 1064 laser

Some industrial plastics are more suitable for laser marking than other materials. In some cases, the color contrast achievable by using a laser does not meet the readability and high quality marking required by fast marking techniques. However, this problem can be solved by the use of special laser-sensitive additives such as fillers, stabilizers and non-fading pigments. This greatly improves the optional experimental study for laser marking materials. Plastics commonly suitable for these experiments are polyethylene, polystyrene, polyoxymethylene, polyurethane, polypropylene, polyvinyl chloride.

Plastic laser marking

Laser absorption characteristics of different plastics

In order to be used for laser marking, plastic must absorb a certain amount of laser beam. At the macro level, most plastics only absorb ultraviolet and far infrared rays in the electromagnetic spectrum (CO2 laser, wavelength 10.6 microns). However, by using additives, fillers and pigments, the absorption characteristics of the material can be altered to increase its ability to absorb laser beams in the near-infrared (1064 nm) or visible green (532 nm) bands. This allows for faster processing and better contrast. It is always recommended to test with different laser technologies on the material you want to use to see which is the right one.

Most of the lasers used for marking emit red light at a wavelength of 1064 nm. But tools designed specifically for processing plastic and semiconductor materials enable lasers to operate in the green (532 nm) and ultraviolet (355 nm) range. The application of ultraviolet light is particularly interesting because they open up a new era of plastic marking. The energy produced by short-wave ultraviolet light initiates a photochemical reaction but does not destroy the material due to excessive heat input. When processing important materials such as plastics incorporating flame retardants, these laser sources are capable of high-contrast marking at very fast processing speeds with the best surface quality.

355nm laser marking plastic: https://www.rfhtech.com/s9-series-3w-5w-10w-uv-laser_p9.html 

532nm green laser marking plastic: https://www.rfhtech.com/s9-series-532-green-laser-5w-10w_p432.html 

There are four different ways to mark on plastic. Discoloration involves changing its color only under the surface of the material, such as by carbonization. In the engraving method, the surface area of ​​the material is removed by melting and evaporation. The laser foaming method incorporates gas bubbles into the material to cause it to swell and produce a relief effect. Light will produce a diffractive property on the surface of the modified material, resulting in a bright/dark contrast effect. The ablation method is based on the required marking content, by partially removing the surface material, leaving a mark with a concave-convex effect.

How to choose the widest range of best marking techniques depends on the particular application of the marking, the type of plastic and the wavelength of the laser source. The color change method is suitable for most thermal plastics. The carbonization method produces a dark marking effect on a bright background, and in most cases a laser with a wavelength of 532 or 355 nm is used. The foaming rule is used to produce a bright marking effect on a dark background (usually black) using a laser with a wavelength of 1064 nm from a running laser source. Engraving is more suitable for thermoset and elastic plastics (in most cases the laser has a wavelength of 1064 nm).

Lasers used for marking typically produce radiation in the infrared wavelength range. Green lasers and UV lasers target plastic and semiconductor materials. In special marking applications, the use of UV wavelengths opens up new possibilities for laser marking on plastics. The short wavelength directly produces a photochemical reaction with the plastic composite without heating, so that it does not damage the material; especially some of the more critical materials, plastics containing flame retardants, or sensitive electronic components. These lasers perform high-contrast marking at very high speeds without any negative impact on surface quality.

Der wichtigste Punkt ist, dass der Kunststoff die Laserstrahlung weitgehend absorbieren muss. Die biomakromolekulare Struktur von Kunststoffen absorbiert typischerweise nur Licht im ultravioletten Bereich und im fernen Infrarot (IR)-Bereich (Wellenlänge 10,6 m). Additive, Füllstoffe und Pigmente in technischen Kunststoffen haben einen großen Einfluss auf die Absorptionseigenschaften des Materials, sodass der Kunststoff den Laserstrahl im nahen Infrarotbereich oder im sichtbaren grünen Laserbereich besser absorbieren kann. Mit diesem Verfahren können eine höhere Markierungsgeschwindigkeit und ein besserer Kontrast erzielt werden.